Abstract

A new polymeric, two-dimensional compound [Fe(4,4-bpy)(µ1,5-dca)2].0.24(4,4-bpy).0.5(EtOH) (1), in which dca= dicyanamide and 4,4-bpy = 4,4-bipyridine, has been synthesized under solvothermal conditions and fully characterized by elemental analysis, FT-IR spectroscopy and X-ray single crystal diffraction. Structural analysis of compound 1 showed it is a novel two dimensional coordination polymer, constructed from repetition of 4,4-bpy and dca as a bidentate bridging ligand. Using the co-ligand 4,4-bpy, lead to completely different structure geometry and network, which confirms the substantial effect of co-ligand. Furthermore, magnetic properties have been performed to understand the correlation structure-properties.

References

[1] C. Genre, E. Jeanneau, A. Bousseksou, D. Luneau, S. A. Borshth, and G. S. Matouzenko,Chem. - A Eur. J., 14, 697–705, (2008).
[2] J. Carranza, C. Brennan, J. Sletten, F. Lloret, and M. Julve, J. Chem. Soc. Dalt. Trans.,3164–3170, (2002).
[3] Q. Li and H.-T. Wang, Acta Crystallogr. Sect. C Struct. Chem., 70, 1054–1056, (2014).
[4] K. R. Dunbarb, R. March, and A. April, 954–958, (2001).
[5] S. Benmansour, C. Atmani, F. Setifi, S. Triki, M. Marchivie, C.J. G_omez-García,Coord. Chem. Rev. 254 (2010) 1468-1478.
[6] S. Benmansour, F. Setifi, S. Triki, J.-Y. Salaün, F. Vandevelde, J. Sala-Pala,C.J. G_omez-García, T. Roisnel, Eur. J. Inorg. Chem. 2007 (2007) 186-194.
[7] A. Miyazaki, K. Okabe, T. Enoki, F. Setifi, S. Golhen, L. Ouahab, T. Toita,J. Yamada, Synth. Met. 137 (2003) 1195-1196.
[8] F. Setifi, E. Milin, C. Charles, F. Th_etiot, S. Triki, C.J. G_omez-García, Inorg. Chem. 53(2014) 97-104.
[9] Z. Setifi, F. Setifi, L. El Ammari, M. El-Ghozzi, J. Sopkov_a-de Oliveira Santos,H. Merazig, C. Glidewell, Acta Crystallogr. Section C Struct. Chem. 70 (2014) 19-22.
[10] C. Yuste, A. Bentama, N. Marino, D. Armentano, F. Setifi, S. Triki, F. Lloret,M. Julve, Polyhedron 28 (2009) 1287-1294.
[11] S. Benmansour, F. Setifi, S. Triki, C.J. G_omez-García, Inorg. Chem. 51 (2012) 2359-2365.
[12] E. Gungor, Y. Yahsi, H. Kara, A. Caneschi, CrystEngComm 17 (2015) 3082-3088.
[13] U. Erkarslan, G. Oylumluoglu, M.B. Coban, E. €Oztürk, H. Kara, Inorg. Chim. Acta. 445(2016) 57-61.
[14] H. Kara, A. Azizoglu, A. Karaoglu, Y. Yahsi, E. Gungor, A. Caneschi, L. Sorace, CrystEngComm 14 (2012) 7320.
[15] Z. Setifi, B. Gaamoune, H. Stoeckli-Evans, D.-A. Rouag, F. Setifi, Acta Crystallogr. Sect. CCryst. Struct. Commun. 66 (2010) m286-m289.
[16] Z. Setifi, M. Ghazzali, C. Glidewell, O. P_erez, F. Setifi, C.J. G_omez-García, J. Reedijk, Polyhedron 117 (2016) 244-248.
[17] A. M. Kutasi, A. R. Harris, S. R. Batten, B. Moubaraki, and K. S. Murray, Cryst.Growth Des., 4, 605–610, (2004).
[18] J. L. Manson, A. M. Arif, C. D. Incarvito, L. M. Liable-Sands, A. L. Rheingold, and J.S. Miller, J. Solid State Chem., 145, 369–378, (1999).
[19] A. Claramunt, A. Escuer, F. a. Mautner, N. Sanz, and R. Vicente, J. Chem. Soc. Dalt.Trans., 2627–2630, (2000).
[20] J. L. Manson, D. W. Lee, A. L. Rheingold, and J. S. Miller, Inorg. Chem., 37, 5966–5967, (1998).
[21] J. L. Manson, C. D. Incarvito, A. L. Rheingold, and J. S. Miller, J. Chem. Soc. Dalt.Trans., 3705–3706, (1998).
[22] P. Jensen et al., J. Solid State Chem., 145, 387–393, (1999).
[23] J. L. Manson, A. M. Arif, and J. S. Miller, J. Mater. Chem., 9, 979–983, (1999).
[24] S. R. Batten et al., J. Chem. Soc. Dalt. Trans., 2987–2997, (1999).
[25] S. R. Batten and K. S. Murray, Coord. Chem. Rev., 246, 103–130, (2003).
[26] A. Escuer, F. A. Mautner, N. Sanz, and R. Vicente, Inorg. Chem., 39, 1668–1673,(2000).
[27] S. Triki, F. Thétiot, J.-R. Galán-Mascarós, J. Sala Pala, and K. R. Dunbar, New J. Chem.,25, 954–958, (2001).
[28] S. Konar, U. Saha, M. Dolai, and S. Chatterjee, J. Mol. Struct., 1075, 286–291, (2014).
[29] M. Biswas, S. R. Batten, P. Jensen, and S. Mitra, Aust. J. Chem., 59, 115–117, (2006).
[30] Bruker APEX2, SADABS and SAINT, Bruker AXS Inc., Madison, Wisconsin, USA,(2013).
[31] G. M. Sheldrick, Acta Cryst. A64 (2008) 112-122.
[32] G. M. Sheldrick, Acta Cryst. C71 (2015) 3-8.
[33] J.-H. Luo, M.-C. Hong, R. Cao, Y.-C. Liang, Y.-J. Zhao, R.-H. Wang, J.-B. Weng, Polyhedron21 (2002) 893-898.
[34] F. Reuter, E. Rentschler, Polyhedron 52 (2013) 788-796.
[35] F. Setifi, P. Konieczny, C. Glidewell, M. Arefian, R. Pelka, Z. Setifi, M. Mirzaei,J. Mol. Struct. 1149 (2017) 149-154.
[36] Z. Setifi, F. Setifi, S.W. Ng, A. Oudahmane, M. El-Ghozzi, D. Avignant, Acta Crystallogr.Section E Struct. Rep. 69 (2013) m12-m13.
[37] Z. Setifi, K.V. Domasevitch, F. Setifi, P. Mach, S.W. Ng, V. Pet_rí_cek, M. Du_sek, ActaCrystallogr. Sect. C Cryst. Struct. Commun. 69 (2013) 1351-1356.
[38] Z. Setifi, F. Setifi, H. Boughzala, A. Beghidja, C. Glidewell, Acta Crystallogr. Section CStruct. Chem. 70 (2014) 465-469.
[39] R.D. Shannon, C.T. Prewitt, Acta Crystallogr. Sect. B Strct. Crystallogr. Cryst. Chem. 25(1969) 925-946.